Bis [tris (triméthylsilyl) methyl] diphosphene structure et réactivité

J Escudie, C Couret, H Ranaivonjatovo…

Index: Escudie, J.; Couret, C.; Ranaivonjatovo, H.; Satge, J.; Jaud, J. Phosphorus and Sulfur and the Related Elements, 1983 , vol. 17, p. 221 - 236

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Citation Number: 33

Abstract

Abstract Some aspects of the reactivity of disphosphene RP [dbnd] PR 1 (R [dbnd](Me3Si) 3C) are described, particularly reduction (LiAlH4), electrophilic additions (HCl, Cl2), heterocyclisation reactions (S8). The very bulky (Me3 Si) 3C group well stabilizes the adducts RP (H) P (H) R 5, RP (H) P (Cl) R 6, RP (H) Cl 7, RP (Cl) P (Cl) R 8, 11 such compounds being often unstable. Structure of 1 was determined by single crystal X-ray ...