Photochemical processes on chloromethyl formate and vinyl formate in low-temperature matrices: infrared spectra and ab initio calculations on chloromethanol and …

…, M Dahlqvist, J Murto, M Rasanen

Index: Kunttu, Henrik; Dahlqvist, Martti; Murto, Juhani; Raesaenen, Markku Journal of Physical Chemistry, 1988 , vol. 92, # 6 p. 1495 - 1502

Full Text: HTML

Citation Number: 26

Abstract

The UV photodecomposition of chloromethyl formate and vinyl formate has been studied in low-temperature noble gas matrices at wavelengths between 200 and 260 nm. Two distinct channels in cage photolysis were observed:(i) CIHzCOCHOClH2COH+ CO; HzCCHOCHO- HzCCHOH+ CO.(ii) CIHzCOCHO-HzCO+ HC1+ CO HzCCHOCHO-CH3CH0+ CO. There is a well-established wavelength dependence influencing the product ratios in these ...

Related Articles:

Stability and infrared spectra of mono-, di-, and trichloromethanol

[Wallington; Schneider; Barnes; Becker; Sehested; Nielsen Chemical Physics Letters, 2000 , vol. 322, # 1-2 p. 97 - 102]

Rate coefficients for the reactions of chlorine atoms with methanol and acetaldehyde

[Tyndall; Orlando; Kegley-Owen; Wallington; Hurley International Journal of Chemical Kinetics, 1999 , vol. 31, # 11 p. 776 - 784]

Rate coefficient for the reaction of hydroxymethyl radicals with chlorine and infrared spectra of chloromethanol and dichloromethanol

[Tyndall, Geoffrey S.; Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F. Journal of Physical Chemistry, 1993 , vol. 97, # 8 p. 1576 - 1582]

Kinetic study of hydrolysis of benzoates. Part XXIII—Influence of the substituent and temperature on the kinetics of the alkaline hydrolysis of alkyl benzoates in …

[Nummert, Vilve; Piirsalu, Mare Journal of Physical Organic Chemistry, 2002 , vol. 15, # 6 p. 353 - 361]

Kinetics of the reactions between sulfide radical cation complexes,[S∴ S]+ and [S∴ N]+, and superoxide or carbon dioxide radical anions

[Merenyi, Gabor; Lind, Johan; Eberson, Lennart Acta Chemica Scandinavica, 1998 , vol. 52, # 1 p. 62 - 66]

More Articles...