Organotin diphenylmonothiophosphinates. Crystal structure of bis (diphenylmonothiophosphinato) dimethyltin (IV), Me 2 Sn (OSPPh 2) 2

…, F Caruso, M Rossi, B Mahieu, M Gielen

Index: Silvestru, C.; Haiduc, I.; Caruso, F.; Rossi, M.; Mahieu, B.; Gielen, M. Journal of Organometallic Chemistry, 1993 , vol. 448, # 1-2 p. 75 - 82

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Citation Number: 21

Abstract

Abstract Organotin (IV) diphenylmonothiophosphinates, R n Sn (OSPPh 2) 4-n (R Me, n Bu, Bz, Ph, Cy; n= 2 and 3) have been synthesized in good yields by reactions of organotin halides with ammonium diphenylmonothiophosphinate. The compounds have been characterized by infrared and NMR spectra, and two representative compounds were also studied by 119m Sn-Mössbauer spectroscopy. The structure of bis ( ...