A Novel [FeFe] Hydrogenase Model with a (SCH2) 2P O Moiety

…, P Schollhammer, M El-khateeb, W Weigand

Index: Apfel, Ulf-Peter; Goerls, Helmar; Felton, Greg A. N.; Evans, Dennis H.; Glass, Richard S.; Lichtenberger, Dennis L.; Weigand, Wolfgang Helvetica Chimica Acta, 2012 , vol. 95, # 11 p. 2168 - 2175

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Citation Number: 11

Abstract

A novel [FeFe]-hydrogenase model complex containing phosphine oxide in the dithiolato ligand, namely [Fe2 (CO) 6][(μ-SCH2) 2 (Ph) P O](1), has been synthesized and characterized. Complex 1 was prepared via the reaction of equimolar quantities of (μ-LiS)