Ozonolysis of olefins adsorbed on polyethylene: a new access to ozonides by cycloadditions of carbonyl oxides to ketones

K Griesbaum, W Volpp, R Greinert

Index: Griesbaum, Karl; Volpp, Willi; Greinert, Reinhard Journal of the American Chemical Society, 1985 , vol. 107, # 18 p. 5309 - 5310

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Citation Number: 10

Abstract

1 2 3 4 spherical particles, maximum size 20 pm; supplier, Serva Feinbiochemica, Heidelberg, FRG). The adsorption of 1 (2.11 g on 60.0 g of polyethylene) was carried out at ambient temperatures and the ozone treatment at-78 OC for 4 h with 80 L of a gas stream containing 1.1 mmol of ozone per liter. The products were extracted with diethyl ether at ambient temperatures and the combined extracts were distilled at 15 torr and ambient ...

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