Thiabenzenes. Reassessment of their chemical and physical properties

BE Maryanoff, J Stackhouse…

Index: Maryanoff,B.E. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 2718 - 2742

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Citation Number: 50

Abstract

Abstract: The syntheses of divers thiabenzene systems are described, and several chemical and physical properties of this class of compounds are evaluated. Observations are recorded which point to the similarity between thiabenzenes and acyclic sulfonium ylides: both classes of compounds are stabilized toward thermal decomposition by substituents which delocalize or stabilize electronic charge, both classes undergo thermal Stevens ...