Preparation of novel metal dithiocarbamate complexes containing ω-OH group. Stabilization effect of the OH group on the HNCS 2-Mt linkage

R Nomura, S Fujii, A Takabe, H Matsuda

Index: Nomura, Ryoki; Fujii, Satoru; Takabe, Akihisa; Matsuda, Haruo Polyhedron, 1989 , vol. 8, p. 1891 - 1896

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Citation Number: 4

Abstract

Abstract The direct condensation between metal oxide powders (Zn II, In III, Sb III and Bi III) and dithiocarbamic acids, prepared by the reaction of ethanolamine or 1, 3-propanolamine with CS 2, gave corresponding metal dithiocarbamate complexes in good yields. Although antimony and bismuth dithiocarbamates decomposed up to 80 C to give elimination products such as oxazolidine-2-thione, thiazolidine-2-thione or bis (3-hydroxypropyl) ...