Thermal Rearrangement of Silanecarboxylate Esters1

AG Brook, RJ Mauris

Index: Brook; Mauris Journal of the American Chemical Society, 1957 , vol. 79, p. 971

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Citation Number: 27

Abstract

The evolution of carbon monoxide at or slightly above the melting point appears to be a characteristic property of silanecarboxylic and germanecarboxylic acids and esters. This thermal instability and the attendant rearrangement, as exemplified by triphenylsilanecarboxylic acid,* v3 triphenylgermanecarboxylic acid, and their esters, 2 appeared to us to be worthy of investigation. Since the thermal decompositions of the ...