The Journal of organic chemistry

Employment of palladium pincer-complexes in phenylselenylation of organohalides

OA Wallner, KJ Szabó

Index: Wallner, Olov A.; Szabo, Kalman J. Journal of Organic Chemistry, 2005 , vol. 70, # 23 p. 9215 - 9221

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Citation Number: 40

Abstract

Palladium pincer-complex-catalyzed selenylation of propargyl-, allyl-, benzyl-, and benzoyl halides could be achieved under mild reaction conditions employing trimethylstannylphenylselenide as selenylating agent. This reaction has a high functional group tolerance as carbmethoxy, tosylamino, nitro, aryl bromide, and unprotected hydroxy groups are tolerated. Mechanistic studies indicate that the catalytic cycle is initiated by ...

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