An Efficient and General Iron??Catalyzed Arylation of Benzyl Alcohols and Benzyl Carboxylates

I Iovel, K Mertins, J Kischel, A Zapf…

Index: Iovel, Irina; Mertins, Kristin; Kischel, Jette; Zapf, Alexander; Beller, Matthias Angewandte Chemie - International Edition, 2005 , vol. 44, # 25 p. 3913 - 3917

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Citation Number: 248

Abstract

Functionalized arenes and heteroarenes are of outstanding importance as pharmaceuticals, agrochemicals, fine and bulk chemicals. Hence, the development of environmentally benign CÀC coupling reactions of arenes is an important topic of organometallic chemistry and catalysis. Elegant examples of direct CÀH transformations of arenes [1] include the addition of olefins to acetophenones (Murai reaction)[2] and aromatic imines,[3] novel additions of ...

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