Organic letters

Scope and Limitations of 1, 3, 5-Hexatriene Derivatives in Regioselective Cobalt-Catalyzed Reactions

A Schmidt, G Hilt

Index: Schmidt, Anastasia; Hilt, Gerhard Organic Letters, 2013 , vol. 15, # 11 p. 2708 - 2711

Full Text: HTML

Citation Number: 7

Abstract

Applications of 1, 3, 5-hexatriene derivatives in atom-economic cobalt-catalyzed transformations, such as the Diels–Alder reaction with alkynes, the 1, 4-hydrovinylation reaction with terminal alkenes, and the 1, 4-hydrohexatrienylation reaction, are investigated. In all cases, regioselective transformations were found to generate cyclic derivatives such as stilbenes or acyclic products with a high control of the double bond geometry in the ...

Related Articles:

Polymer-supported Sulfinimidoyl Chloride as a Useful Reagent for Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds.

[Matsuo, Jun-ichi; Kawana, Asahi; Pudhom, Khanitha; Mukaiyama, Teruaki Chemistry Letters, 2002 , # 2 p. 250 - 251]

Attachment of carbonyl functionalities onto olefins via copper-promoted radical reaction of dichloromethylcyanides

[Kamijo, Shin; Yokosaka, Shinya; Inoue, Masayuki Tetrahedron, 2012 , vol. 68, # 26 p. 5290 - 5296]

Umpolung of. pi.-allylpalladium intermediates. A chemoselective reductive elimination of diols

[Trost, Barry M.; Tometzki, Gerald B. Journal of Organic Chemistry, 1988 , vol. 53, # 4 p. 915 - 917]

An efficient synthesis of α, β??unsaturated aldehydes by a four??carbon unit extension of Grignard reagents

[Cloux, Roland; Schlosser, Manfred Helvetica Chimica Acta, 1984 , vol. 67, p. 1470 - 1474]

Polymer-supported sulfinimidoyl chlorides: A convenient reagent for oxidation of alcohols

[Matsuo, Jun-ichi; Kawana, Asahi; Yamanaka, Hiroyuki; Kamiyama, Hiroaki Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 7 p. 1433 - 1440]

More Articles...