The selective functionalization of saturated hydrocarbons. Part 36. Stereoselectivity studies of Gif-type reactions

DHR Barton, W Chavasiri

Index: Barton, Derek H. R.; Chavasiri, Warinthorn Tetrahedron, 1997 , vol. 53, # 8 p. 2997 - 3004

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Citation Number: 5

Abstract

The stereoselectivity of various Gif-type reactions was evaluated using trans-1, 4- dimethylcyclohexane as a chemical probe. The results revealed that these reactions were moderately stereoselective. The outcome of the reactions was preferentially formed in the more stable equatorial configuration.