Generation and Spectroscopic Identification of ClCNS, ClNCS and NCCNS

M Krebsz, G Tarczay, T Pasinszki

Index: Krebsz, Melinda; Tarczay, Gyoergy; Pasinszki, Tibor Chemistry - A European Journal, 2013 , vol. 19, # 50 p. 17201 - 17208

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Citation Number: 5

Abstract

Abstract The photolysis of four chloro-substituted thiadiazoles (3, 4-dichloro-, 3-chloro-and 3- chloro-4-fluoro-1, 2, 5-thiadiazole; 3, 5-dichloro-1, 2, 4-thiadiazole) and 3, 4-dicyano-1, 2, 5- thiadiazole was investigated in inert solid-argon matrices at cryogenic temperatures by means of UV irradiation at selected wavelengths of 254 and 280 nm. The photolysis products were identified by mid-IR and UV spectroscopy. Evidence for the existence of ...