Photoreaction of nitroso-compounds in solution. Part XIV. Reactions of amido-radicals

YL Chow, JNS Tam

Index: Chow,Y.L.; Tam,J.N.S. Journal of the Chemical Society [Section] C: Organic, 1970 , p. 1138 - 1141

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Citation Number: 3

Abstract

N-Aralkylacetamido-radicals, generated by photolysis of the corresponding N-nitroso- amides in various solvents, underwent extensive β-scission of C–H and C–C bonds, in benzene solution, shown by isolation of the appropriate fragmentation products. Although the reactions of amido-radicals were similar to those of alkoxy-radicals, β-scission of the C– Ar bond was not detected. Oxygen did not quench the primary photo-processes nor ...