Synthesis of novel 1, 3, 5-dithiazine derivatives

…, NI Protsuk, AI Albanov, AS Nakhmanovich…

Index: Glotova; Protsuk; Albanov; Nakhmanovich; Lopyrev Russian Journal of General Chemistry, 2003 , vol. 73, # 5 p. 789 - 793

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Abstract

Abstract The reactions of benzoylacetylene, propiolic acid, and methyl propiolate with 2, 4- dithiobiuret and 1-substituted and 1, 5-disubstituted 2, 4-dithiobiurets in glacial AcOH in the presence of HClO 4 or BF 3· Et 2 O were used to obtain 2-substituted 4-amino-6-imino-1, 3, 5-dithiazinium perchlorates or trifluoroborates, respectively.

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