Trifluorotelluroacetyl fluoride, its cyclic dimer and precursors: preparation, characterisation and reactivity

J Beck, A Haas, W Herrendorf, H Heuduk

Index: Beck, Johannes; Haas, Alois; Herrendorf, Wolfgang; Heuduk, Harald Journal of the Chemical Society - Dalton Transactions, 1996 , # 23 p. 4463 - 4470

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Abstract

With the synthesis of CF3 (F) CTe, the second, non-resonance stabilised perfluorinated telluracarbonyl has been isolated and characterised by gas-phase IR and mass spectrometry. It was prepared via pyrolysis of the novel compound Me3SnTeC2F5 at 500° C, 10–3 Torr in 40–50% yield. The compound CF3 (F) CTe is only stable at–196° C and dimerises quantitatively a few degrees above this temperature to the corresponding ...

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