Stille coupling reactions catalysed by a polymer supported palladium complex

MM Dell'Anna, A Lofù, P Mastrorilli, V Mucciante…

Index: Dell'Anna, Maria Michela; Lofu, Antonio; Mastrorilli, Piero; Mucciante, Vittoria; Nobile, Cosimo Francesco Journal of Organometallic Chemistry, 2006 , vol. 691, # 1-2 p. 131 - 137

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Citation Number: 36

Abstract

The coupling between aryl iodides and bromides with organostannanes (Stille reaction) has been investigated in the presence of a polymer supported palladium catalyst. The reaction could be performed in air without any activating ligand and with non-dried solvents. The catalyst, which acts by releasing controlled amounts of soluble active species, could be recycled several times in the coupling between Sn (CH3) 4 or nBu3SnPh with iodoarenes ...

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