Free radical induced reduction of C Cl bond in chlorofluoroethers by alcohols and ethers

V Dědek, F Liška, J Fikar, P Kuzmič

Index: Dedek, Vaclav; Liska, Frantisek; Fikar, Jiri; Kuzmic, Petr Journal of Fluorine Chemistry, 1985 , vol. 29, p. 152

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Abstract

Abstract The reduction of C Cl bonds in (2, 2-dichloro-1, 1, 2-tri-fluoroethyl) trichloromethylether (I), dichloromethyl (2, 2-dichloro-1, 1, 2-trifluoroethyl) ether (II) and (2- chloro-1, 1, 2-trifluoroethyl) trichloromethylether (III) by means of alcohols (ethanol, 2- propanol, 2-butanol, 3-pentanol, cyclohexanol) as well as ethers (1, 3-dioxolane, tetrahydrofurane, diethylether) under ultraviolet and γ-60 Co irradiation were studied. ...