Journal of the American Chemical Society

Photochemical transformations. XIII. Photorearrangements of 3-phenylcycloheptene and some phenylnorcaranes

SJ Cristol, CS Ilenda

Index: Cristol,S.J.; Ilenda,C.S. Journal of the American Chemical Society, 1975 , vol. 97, p. 5862 - 5867

Full Text: HTML

Citation Number: 6

Abstract

Abstract: While irradiation of 3-phenylcycloheptene (12) in cyclohexane or acetonitrile did not lead to isomeric products, that in benzene led to a mixture of 2- phenylmethylenecyclohexane (15) and cis-and trans-2-phenylnorcarane (16 and 17) rather than to the anticipated di-*-methane product, endo-(or exo-)-7-phenylnorcarane. endo-7- Phenylnorcarane (13) iso-merized to the exo isomer (14) when irradiated in ketonic ...

Related Articles:

Palladium-Catalyzed Regio-and Stereoselective Reduction of Allylic Compounds with LiHBEt 3. Application to the Synthesis of Co-enzyme Q 10

[Mohri, Mitsunobu; Kinoshita, Hideki; Inomata, Katsuhiko; Kotake, Hiroshi; Takagaki, Hidetsugu; Yamazaki, Keiji Chemistry Letters, 1986 , p. 1177 - 1180]

Palladium-Catalyzed Regio-and Stereoselective Reduction of Allylic Compounds with LiHBEt 3. Application to the Synthesis of Co-enzyme Q 10

[Mohri, Mitsunobu; Kinoshita, Hideki; Inomata, Katsuhiko; Kotake, Hiroshi; Takagaki, Hidetsugu; Yamazaki, Keiji Chemistry Letters, 1986 , p. 1177 - 1180]

Radical ions in photochemistry. 21. The photosensitized (electron transfer) tautomerization of alkenes; the phenyl alkene system

[Arnold, Donald R.; Mines, Shelley A. Canadian Journal of Chemistry, 1989 , vol. 67, p. 689 - 698]

Catalytic dehydration of benzylic alcohols to styrenes by rhenium complexes

[Korstanje, Ties J.; Jastrzebski, Johann T. B. H.; Gebbink, Robertus J. M. Klein ChemSusChem, 2010 , vol. 3, # 6 p. 695 - 697]

Enantioselective protonation of samarium enolates derived from α-heterosubstituted ketones and lactone by SmI 2-mediated reduction

[Nakamura, Yutaka; Takeuchi, Seiji; Ohgo, Yoshiaki; Yamaoka, Makoto; Yoshida, Akihiro; Mikami, Koichi Tetrahedron, 1999 , vol. 55, # 15 p. 4595 - 4620]

More Articles...