Substitution and Addition Reactions of the Fluoroölefins. IV. 1 Reactions of Fluoride Ion with Fluoroölefins2, 3

WT Miller Jr, JH Fried, H Goldwhite

Index: Miller,W.T. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 3091 - 3099

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Citation Number: 83

Abstract

Experimental evidence is presented to show that a potentially broad area of carbon-fluorine chemistry consists of reactions of the fluoroolefins which are brought about by fluoride ion with initial attack on unsaturated carbon. The importance and generality of such reactions is due to the high order of nucleophilic reactivity shown by fluoride ion toward fluoroolefins and to the unique structural relationships which are involved. Reaction of fluoride ion with a ...