Synthetic communications

Reductive Cleavage of S–S Bond by Zn/AlCl3 System: A Novel Method for the Synthesis of Sulfides from Alkyl Tosylates and Disulfides

B Movassagh, A Mossadegh

Index: Movassagh, Barahman; Mossadegh, Amir Synthetic Communications, 2004 , vol. 34, # 13 p. 2337 - 2343

Full Text: HTML

Citation Number: 15

Abstract

Alkyl and aryl disulfides are reduced by zinc powder in the presence of AlCl 3 in aqueous media to yield zinc thiolates. These thiolate anion species then react with alkyl tosylates to give sulfides in high to excellent yields. ... Alkyl and aryl disulfides are reduced by zinc powder in the presence of AlCl 3 in aqueous media to yield zinc thiolates. These thiolate anion species then react with alkyl tosylates to give sulfides in high to excellent yields. ... Historically the chemistry of ...

Related Articles:

A Novel Approach to the Practical Synthesis of Sulfides: An InBr3–Et3SiH Catalytic System Promoted the Direct Reductive Sulfidation of Acetals with Disulfides

[Sakai, Norio; Moritaka, Kohei; Konakahara, Takeo European Journal of Organic Chemistry, 2009 , # 24 p. 4123 - 4127]

The Reduction of Sulfoxides with Phosphorus (V) Chloride/1-Morpholino-1-cyclohexene

[Wakisaka, Morio; Hatanaka, Minoru; Nitta, Hajime; Hatamura, Mariko; Ishimaru, Toshiyasu Synthesis, 1980 , # 1 p. 67 - 68]

A Facile Synthesis of Unsymmetrical Sulfides Under Phase Transfer Conditions

[Hengchang, Chen; Zhenzhong, Liu; Wei, Liu Synthetic Communications, 1990 , vol. 20, # 21 p. 3313 - 3316]

Transformation of β-chalcogeno alkenylboranes into tetrasubstituted olefins

[Gerard, Julien; Hevesi, Laszlo Tetrahedron, 2004 , vol. 60, # 2 p. 367 - 381]

Synthesis of 2, 4-disubstituted 5-aminoimidazoles using microwave irradiation

[Takido, Toshio; Itabashi, Kunio Synthesis, 1987 , # 9 p. 817 - 819]

More Articles...