Organic letters

Anaerobic nitroxide-catalyzed oxidation of alcohols using the NO+/NO· redox pair

M Holan, U Jahn

Index: Holan, Martin; Jahn, Ullrich Organic Letters, 2014 , vol. 16, # 1 p. 58 - 61

Full Text: HTML

Citation Number: 18

Abstract

A new method for alcohol oxidation using TEMPO or AZADO in conjunction with BF3· OEt2 or LiBF4 as precatalysts and tert-butyl nitrite as a stoichiometric oxidant has been developed. The system is based on a NO+/NO· pair for nitroxide reoxidation under anaerobic conditions. This allows the simple, high-yielding conversion of various achiral and chiral alcohols to carbonyl compounds without epimerization and no formation of ...

Related Articles:

Synthesis of naturally occurring diene and trienes by Te/Li exchange on (1Z, 3Z)-butyltelluro-4-methoxy-1, 3-butadiene

[Dabdoub, Miguel J.; Dabdoub, Vania B.; Baroni, Adriano C.M.; Hurtado, Gabriela R.; Barbosa, Sandro L. Tetrahedron Letters, 2010 , vol. 51, # 13 p. 1666 - 1670]

Synthesis and biological activity of α, β, γ, δ-unsaturated aldehydes from diatoms

[Adolph, Sven; Poulet, Serge A.; Pohnert, Georg Tetrahedron, 2003 , vol. 59, # 17 p. 3003 - 3008]

Palladium Catalyzed Cross-Coupling Reaction of Functional Organozinc Reagents with (2 E, 4 E)-and (2 E, 4 Z)-5-Bromopenta-2, 4-dienals: Easy Access to …

[Synthetic Communications, , vol. 33, # 9 p. 1509 - 1521]

Highly stereocontrolled synthesis of (2e, 4z)-dienic esters by alumina catalyst

[Tsuboi, Sadao; Masuda, Toshihide; Makino, Hiroshi; Takeda, Akira Tetrahedron Letters, 1982 , vol. 23, # 2 p. 209 - 212]

Highly stereocontrolled synthesis of (2e, 4z)-dienic esters by alumina catalyst

[Tetrahedron Letters, , vol. 23, # 2 p. 209 - 212]

More Articles...