Synthesis of N-and C-trimethylsilyl-substituded anililes

…, VM Nosova, TI Shulyat'eva, MV Pecherskii

Index: Storozhenko; Belyakova; Starikova; Nosova; Shulyat'eva; Frenkel'; Pecherskii Russian Journal of General Chemistry, 2008 , vol. 78, # 5 p. 892 - 897

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Abstract

Abstract N-Metallation of bromoanilines with ethylmagnesium bromide followed by a reaction with trimethylchlorosilane provided N-mono and N-bis (trimethylsilyl) bromoanilines depending on the structure of substrate. The metallation of bissilylated bromoanilines with butyllithium permitted the introduction of a trimethylsilyl substituent in the aromatic ring. Previously unknown 2-bromo-N, N-bis (trimethylsilyl) aniline, 2, 6-dibromo-N- ...

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