Polar radicals. 17. On the mechanism of iodine atom transfer. A 9-I-2 intermediate

DD Tanner, DW Reed, BP Setiloane

Index: Tanner, Dennis D.; Reed, Darwin W.; Setiloane, B.P. Journal of the American Chemical Society, 1982 , vol. 104, # 14 p. 3917 - 3923

Full Text: HTML

Citation Number: 37

Abstract

Abstract: The atom-transfer reaction of iodine from an aryl iodide to a phenyl radical has been shown to proceed via a 9-1-2 intermediate. The relative kinetics of the reactions of the intermediate were investigated by studying its mode of decomposition upon formation from the reduction of a series of unsymmetrically substituted diaryliodonium salts. The iodonium salts were reduced by the electron-transfer reactions with several reagents: di-tert-butyl ...

Related Articles:

A novel oxidative transformation of alcohols to nitriles: an efficient utility of azides as a nitrogen source

[Rokade, Balaji V.; Malekar, Sanjeev K.; Prabhu, Kandikere Ramaiah Chemical Communications, 2012 , vol. 48, # 44 p. 5506 - 5508]

Design, synthesis and evaluation of potential inhibitors of HIV gp120–CD4 interactions

[Boussard, Cyrille; Klimkait, Thomas; Mahmood, Naheed; Pritchard, Martin; Gilbert, Ian H. Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 10 p. 2673 - 2676]

Metal??Free Arylation of Oxygen Nucleophiles with Diaryliodonium Salts

[Jalalian, Nazli; Petersen, Tue B.; Olofsson, Berit Chemistry--A European Journal, 2012 , vol. 18, # 44 p. 14140 - 14149,10]

A Simple Synthesis of Nitriles from Aldoximes (1)

[Venkat Narsaiah; Sreenu; Nagaiah Synthetic Communications, 2006 , vol. 36, # 2 p. 137 - 140]

CuI Nanoparticles for C− N and C− O Cross Coupling of Heterocyclic Amines and Phenols with Chlorobenzenes

[Sreedhar; Arundhathi; Reddy, P. Linga; Kantam, M. Lakshmi Journal of Organic Chemistry, 2009 , vol. 74, # 20 p. 7951 - 7954]

More Articles...