Synthesis and valence orbital structures of azacycl [3.3. 3] azines in a systematic series

MA Rossman, NJ Leonard, S Urano…

Index: Rossman,M.A.; Leonhard,N.J.; Urano,S. Journal of the American Chemical Society, 1985 , vol. 107, p. 3884

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Citation Number: 25

Abstract

(1, 3, 4, 6, 8, 9b-hexaazaphenalene) are reported. The syntheses were abbreviated in that they consisted of a two-step procedure whereby the appropriate diaminoazine was treated with methyl N-cyanomethanimidate and NaOMe in MeOH to give the corresponding bis (N'- cyano-N-formamidino) azines and these were subjected to short vacuum pyrolysis to afford the azacyc1 [3.3. 3] azines. The valence orbital electronic structure of this series of ...