Isomerization of alkylphosphites. III. The synthesis of n-alkylphosphonic acids

GM Kosolapoff

Index: Kosolapoff Journal of the American Chemical Society, 1945 , vol. 67, p. 1182

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Citation Number: 105

Abstract

Summary 1. Dicyclopentadiene reacts with hydrochloric, hydrobromic, hydriodic and thiocyanic acids to yield unsaturated addition-rearrangement products. I t also adds organic carboxylic acids to one of itsdouble bonds to yield esters of hydroxy-dihydro-nor- dicyclopentadiene. These reactions are catalyzed by hydrogen ions or by acidic catalysts. Thioglycolic acid adds to dicyclopentadiene to yield an unsaturated thioether instead of an ...