Bulletin of the Chemical Society of Japan

Catalytic Esterification of Alcohols, Carboxylic Acids and Transesterification Reactions with Cerium (IV) Triflate.

N Iranpoor, M Shekarriz

Index: Iranpoor, Nasser; Shekarriz, Marzieh Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 3 p. 455 - 458

Full Text: HTML

Citation Number: 47

Abstract

Esterification reactions of alcohols with acetic, chloroacetic, trifluoroacetic, propionic, stearic, and benzoic acids were catalyzed with Ce (OTf) 4 in a solvent or under solvent-free conditions with high yields. The formylation and acetylation of primary and secondary alcohols were also easily achieved in ethyl formate and ethyl acetate. A high retention of the configuration was observed in the acetylation and formylation of (−)-menthol.

Related Articles:

A facile, catalytic and environmentally benign method for esterification of carboxylic acids and transesterification of carboxylic esters with nearly equimolar amounts of …

[Bose, D. Subhas; Satyender, Apuri; Das, A. P. Rudra; Mereyala, Hari Babu Synthesis, 2006 , # 14 p. 2392 - 2396]

Preparation of acyl fluorides with hydrogen fluoride-pyridine and 1, 3-dicyclohexylcarbodiimide

[Chen, Chinpiao; Chien, Chin-Tzu; Su, Chu-Hsiang Journal of Fluorine Chemistry, 2002 , vol. 115, # 1 p. 75 - 77]

Preparation of acyl fluorides with hydrogen fluoride-pyridine and 1, 3-dicyclohexylcarbodiimide

[Chen, Chinpiao; Chien, Chin-Tzu; Su, Chu-Hsiang Journal of Fluorine Chemistry, 2002 , vol. 115, # 1 p. 75 - 77]

A catalogue of multiple congenital anomaly syndromes

[Ellis; Rabinovitz Chem. Zentralbl., 1918 , vol. 89, # I p. 611]

A catalogue of multiple congenital anomaly syndromes

[Ellis; Rabinovitz Chem. Zentralbl., 1918 , vol. 89, # I p. 611]

More Articles...