Reactions in moderately concentrated acids. 2. Solvation effects in the acid-catalyzed hydration of olefins and acetylenes
G Modena, F Rivetti, G Scorrano…
Index: Modena,G. et al. Journal of the American Chemical Society, 1977 , vol. 99, p. 3392 - 3395
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Citation Number: 33
Abstract
Abstract: Rate data for the hydration of substituted styrenes and phenylacetylenes and of rrans-3-hexene and 3-herqne in moderately concentrated aqueous sulfuric acid solutions have been analyzed in terms of the proper linear free energy relationship (for &E2 type mechanisms) discussed in the previous paper. The analysis indicates that the solvation requirements of the transition states of the reaction and hence of the corresponding ...
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