Mechanistic and exploratory organic photochemistry. 96. New photochemical rearrangement. Cyclopropyl-. pi.-methane rearrangement
HE Zimmerman, CJ Samuel
Index: Zimmerman,H.E.; Samuel,C.J. Journal of the American Chemical Society, 1975 , vol. 97, # 14 p. 4025 - 4036
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Citation Number: 17
Abstract
Abstract: The photochemistry of 3-(2, 2-diphenylcyclopropyl)-3-methyl-l, I-diphenyl-1-butene was investigated in order to ascertain the reactivity of a system having one T moiety and one cyclopropyl ring attached to a saturated carbon. Only the singlet excited state proved reactive. As photochemical products there were obtained 1, I-diphenylethylene, 2-methyl-1, l- diphenyl-I-propene, 1, I-diphenylbutadiene, 4-methyl-l, l-diphenyl-l, 3-pentadiene, and 3-( ...
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[Zimmerman, Howard E.; Hoffacker, Kurt D. Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6526 - 6534]
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