Chiral imidate–ferrocenylphosphanes: synthesis and application as P, N-ligands in iridium (i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized …

…, W Kimpe, JL Goeman, J Van der Eycken

Index: Bert, Katrien; Noel, Timothy; Kimpe, Wim; Goeman, Jan L.; Van Der Eycken, Johan Organic and Biomolecular Chemistry, 2012 , vol. 10, # 42 p. 8539 - 8550

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Citation Number: 12

Abstract

A small library of chiral imidate–ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium (I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).

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