Novel photoreaction using diphenyl disulfide derivatives: Photoinduced oxidation of allyl alcohol

T Tsuboi, Y Takaguchi, S Tsuboi

Index: Tsuboi, Takaaki; Takaguchi, Yutaka; Tsuboi, Sadao Bulletin of the Chemical Society of Japan, 2008 , vol. 81, # 3 p. 361 - 368

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Citation Number: 8

Abstract

Allyl alcohols are oxidized to acrylaldehydes using diphenyl disulfide derivatives upon photoirradiation. The reaction occurs via α-hydrogen abstraction by a sulfanyl radical. Interestingly, the oxidation reaction occurs in moderate yield when a dendrimer disulfide is used as a mediator.

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