Selective Functionalization of a Variety of Hydrocarbon C (sp3)–H Bonds Initiated by Cp* W (NO)(CH2CMe3)(η3-CH2CHCHPh)

RJ Wakeham, RA Baillie, BO Patrick, P Legzdins…

Index: Izquierdo, Javier; Rodriguez, Santiago; Gonzalez, Florenci V. Organic Letters, 2011 , vol. 13, # 15 p. 3856 - 3859

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Abstract

... a result of the electronic asymmetry at the metal center, which is caused by both the nitrosyl and the cyclopentadienyl ligands.(4, 6) This effect is manifested in the solid-state molecular structures of the complexes by different allyl C–C bond lengths and in solution by 13 C NMR ...