Charge Delocalization of 1, 4-Benzenedicyclometalated Ruthenium: A Comparison between Tris-bidentate and Bis-tridentate Complexes

…, WW Yang, CJ Yao, HY Xie, YW Zhong

Index: Sui, Long-Zhen; Yang, Wen-Wen; Yao, Chang-Jiang; Xie, Hai-Yan; Zhong, Yu-Wu Inorganic Chemistry, 2012 , vol. 51, # 3 p. 1590 - 1598

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Citation Number: 26

Abstract

A dimetallic biscyclometalated ruthenium complex,[(bpy) 2Ru (dpb) Ru (bpy) 2] 2+, with a tris- bidentate coordination mode was prepared. The electronic properties of this complex were studied by electrochemical and spectroscopic analysis and DFT/TDDFT calculations on both rac and meso isomers. The charge delocalization of the corresponding one-electron- oxidized complex was studied with spectroscopic, theoretical, and EPR analysis and ...

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