Russian Chemical Bulletin

Dehydrochlorination of chloroform by N-methyl-N, N-bis (silatranylmethyl) amine

NF Lazareva, IM Lazarev

Index: Lazareva; Lazarev Russian Chemical Bulletin, 2011 , vol. 60, # 3 p. 598 - 600

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Citation Number: 3

Abstract

Abstract N, N-Bis (silatranylmethyl) methylamine 1 reacts with chloroform resulting in amine hydrochloride 2 and dichlorocarbene. The formation of the latter was proved by a cyclopropanation reaction and insertion into the Si-H bond. In the presence of cyclohexene,