Journal of Organometallic Chemistry

Über reaktionen mit aluminiumalkylen XII. Konkurrierende eigenschaften von alkylaluminiumverbindungen: reaktionspartner und friedel-crafts-katalysator

H Reinheckel, R Gensike

Index: Reinheckel,H.; Gensike,R. Journal of Organometallic Chemistry, 1968 , vol. 13, p. 45 - 51

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Citation Number: 3

Abstract

Abstract The double effect of ethylaluminium sesquichloride on ω-phenylcarboxylic acid chlorides with a chain length of C 3 to C 6, namely alkylation and Friedel-Crafts cyclization was investigated. It was established that the two alternatives are possible only with 4- phenylbutyryl chloride. Depending on the reaction conditions, both alkylation and cyclization yield 6-phenyl-3-hexanone, as well as 1-tetralone. The other three ω-phenylcarboxylic ...

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