Carbon-13 nuclear magnetic resonance of organophosphorus compounds. X. Ring-size variation in heterocyclic phosphines, phosphonium salts, and phosphine …

GA Gray, SE Cremer, KL Marsi

Index: Gray,G.A. et al. Journal of the American Chemical Society, 1976 , vol. 98, p. 2109 - 2118 Full Text View citing articles Show Details Grim,S.O. et al. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, Biochemie, Biophysik, Biologie, 1971 , vol. 26b, p. 184 - 190

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Citation Number: 52

Abstract

Abstract: I3C chemical shifts and 13C-31P nuclear spin couplings are reported for phosphorus heterocycles with exocyclic substitutions: phenyl, diphenyl, benzylphenyl, and phenyloxide. These saturated heterocycles extend from three-membered (only for the phosphine) through eight-membered rings, using di-n-butyl analogues as examples of unconstrained relatives. Sign determination for several of the 13C-31P couplings in the ...