The Journal of Organic Chemistry

Phosphorus-containing products from the reaction of propargyl alcohols with phosphorus trihalides. 4. Alkyl substituent effects on oxaphospholene formation

RS Macomber, ER Kennedy

Index: Macomber,R.S.; Kennedy,E.R. Journal of Organic Chemistry, 1976 , vol. 41, p. 3191 - 3197

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Citation Number: 60

Abstract

The timer was started and 10-ml aliquots were periodically with- drawn. An infinity aliquot was withdrawn after 10 half-lives. The aliquots were added to 10 ml of a potassium iodide solution, which were contained in nitrogen-swept 250-ml Erlenmeyer flasks. The potassium iodide solution was prepared from 15 g of potassium iodide, 25 g of sodium acetate, and 10 g of sodium carbonate per 100 ml of doubly distilled water solution. After the reaction solution aliquot ...