Tetrahedron

Phase transfer catalysis and homogeneous reactions with β-oxyalkyl radicals from organomercurials

J Barluenga, J López-Prado, PJ Campos, G Asensio

Index: Barluenga, Jose; Lopez-Prado, Joaquin; Campos, Pedro J.; Asensio, Gregorio Tetrahedron, 1983 , vol. 39, # 17 p. 2863 - 2868

Full Text: HTML

Citation Number: 11

Abstract

β-Alkoxy-and β-hydroxyalkyl radicals generated by sodium borohydride reduction of oxymercurials react with electron deficient olefins to give addition compounds in an homogeneous process. Heterogeneous reactions are also successful in the presence of catalytic amounts of surfactants and provide a superior method for the “one pot” reductive alkylation of oxymercurials.

Related Articles:

Liquid-phase catalytic hydrogenation of unsaturated ethers

[Cerveny, Libor; Sabata, Stanislav; Ruzicka, Vlastimil Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 12 p. 3525 - 3531]

Liquid-phase catalytic hydrogenation of unsaturated ethers

[Cerveny, Libor; Sabata, Stanislav; Ruzicka, Vlastimil Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 12 p. 3525 - 3531]

Peroxometalates immobilized on magnetically recoverable catalysts for epoxidation

[Qiao, Yunxiang; Li, Huan; Hua, Li; Orzechowski, Lars; Yan, Kai; Feng, Bo; Pan, Zhenyan; Theyssen, Nils; Leitner, Walter; Hou, Zhenshan ChemPlusChem, 2012 , vol. 77, # 12 p. 1128 - 1138]

Carbanionen??Umlagerungen durch intramolekulare 1, ω??Protonverschiebung, III. Zur Reaktionsweise von 2??, 3??, 4??und 5??Phenylalkyllithiumverbindungen

[Maercker, Adalbert; Passlack, Michael Chemische Berichte, 1982 , vol. 115, # 2 p. 540 - 577]

The methoxymercuration of some styrene derivatives

[Bassetti, Mauro; Floris, Barbara; Illuminati, Gabriello Journal of Organometallic Chemistry, 1980 , vol. 202, # 4 p. 351 - 362]

More Articles...