Insertion reactions of trifluoromethylcarbene

JH Atherton, R Fields

Index: Atherton,J.H.; Fields,R. Journal of the Chemical Society [Section] C: Organic, 1968 , p. 2276 - 2278

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Citation Number: 13

Abstract

Trifluoromethylcarbene, generated photolytically from 2, 2, 2-trifluorodiazoethane, reacts with the C–H bonds of saturated hydrocarbons in the liquid phase to give high yields of the corresponding insertion products. The primary and secondary C–H bonds in n-butane undergo insertion at essentially the same rate, but the tertiary C–H bond in isobutane is some 30% more reactive than the primary C–H. In the vapour phase very low yields of ...