Synlett

Diversity-oriented approach to macrocyclic cyclophane derivatives via ring-closing metathesis

S Kotha, ME Shirbhate

Index: Kotha, Sambasivarao; Shirbhate, Mukesh E. Synlett, 2012 , vol. 23, # 15 p. 2183 - 2188

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Citation Number: 9

Abstract

Ring-closing metathesis (RCM)[ 6 ] has become one of the most efficient ways to assemble macrocycles.[ 7 ] Several macromolecules are known to play an important role in bioorganic and medicinal chemistry, they possess unique chemical properties and play a pivotal role in host–guest[ 8 ] and supramolecular chemistry.[ 9 ] Synthesis of cyclophane derivatives is a challenging task because of the entropy factors and ring strain involved with these systems. These ...

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