Research on Chemical Intermediates

New approaches to photocatalytic reaction of low concentrations of arylamines in alcohols

A Hosseinnia, M Keyanpour-Rad

Index: Hosseinnia, Azarmidokht; Keyanpour-Rad, Mansoor Research on Chemical Intermediates, 2012 , vol. 38, # 7 p. 1411 - 1420

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Abstract

Abstract Photocatalytic interactions of a series of arylamines, for example 1, 4- phenylenediamine, 1, 2-phenylenediamine, 4-aminophenol, and 2-aminophenol, at low concentrations in typical primary alcohols have been investigated in the presence of anatase TiO 2 nanopowder. GC–MS analysis of the irradiated solutions showed that, except for 1, 2-phenylenediamine, 10 mmol/l alcoholic solutions of the arylamines gave ...