Reactions of tert-butyl peroxy esters. X. Preparation of dialkyl tert-butyl phosphates from dialkyl tert-butylperoxy phosphates. Dialkyl phosphorochloridates, and dialkyl …

G Sosnovsky, EH Zaret, KD Schmitt

Index: Sosnovsky,G. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 336 - 340

Full Text: HTML

Citation Number: 8

Abstract

Dialkyl t-butyl phosphates (1, R= Me, Et, i-Pr) are produced in low yield by the reaction of the corresponding dialkyl t-butylperoxy phosphates (2) with triphenylphosphine (4), and by the reaction of the corresponding dialkyl phosphorochloridites (8) with t-butyl hydroperoxide (7) in the presence of pyridine. Esters 1 (R= Me, Et, n-Pr, i-Pi-, n-Bu, i-Bu, Ph, PhCHB) are produced in high yield by the reaction of the corresponding dialkyl phosphorochloridates ( ...

Related Articles:

Cross-hetero-dehydrogenative coupling reaction of phosphites: a catalytic metal-free phosphorylation of amines and alcohols

[Jones, Simon; Smanmoo, Chaiwat Organic Letters, 2005 , vol. 7, # 15 p. 3271 - 3274]

Substitution??and Elimination??Free Phosphorylation of Functionalized Alcohols Catalyzed by Oxidomolybdenum Tetrachloride

[Liu, Cheng-Yuan; Pawar, Vijay D.; Kao, Jun-Qi; Chen, Chien-Tien Advanced Synthesis and Catalysis, 2010 , vol. 352, # 1 p. 188 - 194]

3-Phosphono-2-(N-cyanoimino) thiazolidine derivatives, new phosphorylating agents for alcohols

[Maezaki, Naoyoshi; Furusawa, Akemi; Hirose, Yuki; Uchida, Shuji; Tanaka, Tetsuaki Tetrahedron, 2002 , vol. 58, # 18 p. 3493 - 3498]

More Articles...