Generation of. BETA.-Keto Radicals from Cyclopropanol Derivatives by the Use of Manganese (III) 2-Pyridinecarboxylate as an Oxidant and Their Reactions with …
N Iwasawa, S Hayakawa, K Isobe, K Narasaka
Index: Iwasawa, Nobuharu; Hayakawa, Satoshi; Isobe, Koichi; Narasaka, Koichi Chemistry Letters, 1991 , p. 1193 - 1196
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Citation Number: 35
Abstract
Various β-keto radicals are generated from cyclopropanol derivatives such as 1-or 2- substituted cyclopropanols and a cyclopropanone hemiacetal by the use of manganese (III) 2-pyridinecarboxylate, and their reactions with electron-rich olefins give cross-addition products in good yields.
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[Iwasawa, Nobuharu; Hayakawa, Satoshi; Funahashi, Masahiro; Isobe, Koichi; Narasaka, Koichi Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 3 p. 819 - 827]