Synthesis and Characterization of Organo-Rare-Earth Metal Monoalkyl Complexes Supported by Carbon σ-Bonded Indolyl Ligands: High Specific Isoprene 1, 4-Cis …

L Guo, X Zhu, G Zhang, Y Wei, L Ning, S Zhou…

Index: Zhu, Xiancui; Wang, Shaowu; Zhou, Shuangliu; Wei, Yun; Zhang, Lijun; Wang, Fenhua; Feng, Zhijun; Guo, Liping; Mu, Xiaolong Inorganic Chemistry, 2012 , vol. 51, # 13 p. 7134 - 7143

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Citation Number: 8

Abstract

Cyclometalation via C–H bond activation is an attractive area of organometallic chemistry, which provides a mild route for constructing a new M–C bond.(1) This process has been incorporated into the development of a new methodology in catalytic synthetic chemistry and envisioned great progress in this field.(2) In contrast with the well-known oxidative addition of a C–H bond catalyzed by late-transition metals, using rare-earth metals as catalysts in catalytic synthetic ...

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