Benign Catalysis with Iron: Unique Selectivity in Catalytic Isomerization Reactions of Olefins

R Jennerjahn, R Jackstell, I Piras, R Franke…

Index: Jennerjahn, Reiko; Jackstell, Ralf; Piras, Irene; Franke, Robert; Jiao, Haijun; Bauer, Matthias; Beller, Matthias ChemSusChem, 2012 , vol. 5, # 4 p. 734 - 739

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Citation Number: 38

Abstract

Abstract The use of noble metal catalysts in homogeneous catalysis has been well established. Due to their price and limited availability, there is growing interest in the substitution of such precious metal complexes with readily available and bio-relevant catalysts. In particular, iron is a “rising star” in catalysis. Herein, we present a general and selective iron-catalyzed monoisomerization of olefins, which allows for the selective ...

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