Palladium (0) catalyzed reaction of 1, 3-diene 1, 4-epiperoxides
M Suzuki, Y Oda, R Noyori
Index: Suzuki, M.; Oda, Y.; Noyori, R. Tetrahedron Letters, 1981 , vol. 22, # 44 p. 4413 - 4416
Full Text: HTML
Citation Number: 32
Abstract
Abstract Reaction of 1, 3-diene 1, 4-epiperoxides with Pd (PPh 3) 4 catalyst forms the corresponding 4-hydroxy enones, syn diepoxides, and 1, 4-diols as the major products. The results are interpreted as being due to competing Pd (0)/Pd (II) and Pd (0)/Pd (I) exchange mechanisms.
Related Articles:
[Noyori, Ryoji; Suzuki, Masaaki Angewandte Chemie, 1984 , vol. 96, # 11 p. 854 - 882]
[Suzuki, Masaaki; Ohtake, Hiroaki; Kameya, Yoshimi; Hamanaka, Nobuyuki; Noyori, Ryoji Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5292 - 5302]