Reaction of Organocobaloxime with Thiol under Irradiation

M Kijima, K Miyamori, T Nakamura, T Sato

Index: Kijima, Masashi; Miyamori, Kiyokatsu; Nakamura, Tomoko; Sato, Takeo Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 9 p. 2549 - 2554

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Citation Number: 11

Abstract

The reactivity of photoactivated organocobaloxime was investigated by the reaction of thiol. Alkyl (pyridine) cobaloxime and ethyl mercaptoacetate were irradiated with a tungsten lamp under anaerobic conditions in an organic solvent to give ethyl alkylthioacetate, diethyl 2, 2′- dithioacetate, and ethoxycarbonylmethylthiocobaloxime. Mechanistic investigations were carried out to determine the reaction course. Sulfide was assumed to be produced via a ...

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