Tetrahedron

Aromatic substitution of olefin—VII: Reactions of lower olefins with benzene by palladium acetate

S Danno, I Moritani, Y Fujiwara

Index: Danno,S. et al. Tetrahedron, 1969 , vol. 25, p. 4809 - 4813

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Citation Number: 24

Abstract

The phenylation of propylene, 1-butene, rans-and cis-butenes, and 1, 3-butadiene with benzene was carried out in the presence of palladium acetate and acetic acid. It was concluded that, although the usual olefins predominantly undergo phenylation, an olefin which can easily form a π-allyl complex gives acetates as major products under the present reaction conditions.

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