Kinetics of the reduction of 1-methylquinolinium cations by 1-benzyl-1, 4-dihydronicotinamide
JW Bunting, NP Fitzgerald
Index: Bunting, John W.; Fitzgerald, Norman P. Canadian Journal of Chemistry, 1985 , vol. 63, p. 655 - 662
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Citation Number: 12
Abstract
The reduction of a series of 3-W-1-methylquinolinium cations (1: W= H, Br, CONH2, CO2CH3, CN, NO2) by 1-benzyl-1, 4-dihydronicotinamide has been investigated. In all cases the kinetically controlled product from these reactions is the appropriate 3-W-1, 4- dihydro-1-methylquinoline. Only for W= Br is any significant amount of the 1, 2-dihydro isomer obtained (15% in this case). This kinetic preference for C-4 attack over C-2 attack ...
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