Studies on Photochemical Reactions of Air Pollutants. VIII. Photochemical Epoxidation of Olefins with NO2 in a Solid-Gas Phase System

…, T OHYA, S KANNO, M HIROBE

Index: Nojima; Ohya; Kanno; Hirobe Chemical and Pharmaceutical Bulletin, 1982 , vol. 30, # 12 p. 4500 - 4506

Full Text: HTML

Citation Number: 11

Abstract

Upon irradiation with a xenon lamp through a Pyrex filter (cut-off below 290 nm), olefinic compounds such as trans-stilbene, cyclohexene, 4, 5-dibromocyclohexene and aldrin reacted with nitrogen dioxide, an air pollutant which induces photochemical smog, in air and gave the corresponding epoxides in good yields, while phenanthrene gave 9, 10- phenanthrenequinone and 9-hydroxy-10-nitrophenanthrene. Furthermore, the ...

Related Articles:

Functionalized organolithium reagents. 8. Novel (. alpha.,. beta.-epoxyalkyl) lithium reagents via the lithiation of organyl-substituted epoxides

[Eisch, John J.; Galle, James E. Journal of Organic Chemistry, 1990 , vol. 55, # 16 p. 4835 - 4840]

Ethylene dications substituted with electron-donating groups

[Ohwada, Tomohiko; Shudo, Koichi Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5227 - 5237]

Bidentates versus monodentates in asymmetric hydrogenation catalysis: Synergic effects on rate and allosteric effects on enantioselectivity

[Norman, David W.; Carraz, Charles A.; Hyett, David J.; Pringle, Paul G.; Sweeney, Joseph B.; Orpen, A. Guy; Phetmung, Hirrahataya; Wingad, Richard L. Journal of the American Chemical Society, 2008 , vol. 130, # 21 p. 6840 - 6847]

The directed ortho metalation connection to aryl-aryl cross coupling. A general regiospecific synthesis of phenanthrols

[Fu, J.-m.; Sharp, M.J.; Snieckus, V. Tetrahedron Letters, 1988 , vol. 29, # 43 p. 5459 - 5462]

Synthesis of Phenanthrene Derivatives. II. 1 Benzoylphenanthrenes and Derivatives

[Bachmann Journal of the American Chemical Society, 1934 , vol. 56, p. 1363 Journal of the American Chemical Society, 1935 , vol. 57, p. 555]

More Articles...